Volume 20 No 8 (2022)
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Assessment of Anticorrosive Coatings with Multicore Microcapsules and Polyaniline Nanoparticles: A Novel Synergistic Approach
U. B. Gawai , P. S. Shisode , C. B. Patil
Abstract
The present investigation reports, successful preparation of polyaniline (PANI) nanoparticles and its
improved corrosion resistance with addition of multicore microcapsules. The multicore microcapsules
were synthesized by in-situ polymerization method, with oil in water emulsion technique separately and
blends of Tung oil and Dehydrated Castor oil (20 % and 30 % DCO) were entrapped in urea formaldehyde
(UF) micro containers. The surface morphology of prepared microcapsules was analysed initially by digital
optical microscope and then with Scanning Electron Microscopy (SEM). The particle size of synthesized
microcapsules was determined by particle size analyser. The core content of the microcapsules was
determined by extraction process using Soxhlet apparatus. The synthesized microcapsules were then
incorporated into epoxy coating to verify their self-healing properties. The improved corrosion resistance
of PANI nanoparticles was then checked by incorporating them along with the synthesized microcapsules
combinations into epoxy coating matrix. Corrosion protection of coated panels were analysed by
immersion in 3.5 % NaCl and 0.5 M HCl solution and studied in comparison with pristine epoxy coated
panels.
Keywords
Microencapsulation, Tung Oil and Dehydrated Castor Oil blend, Polyaniline nanoparticles, Anticorrosive coatings.
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