Volume 20 No 9 (2022)
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Organic Nanoparticles as Sensor for toxic metals in Aqueous Medium Based On Fluorescent quenching
Dhaidan Khalaf Kafi,Hamid A. Fayyadh, Ahmad A. Darweesh
Abstract
Molecule N-[3-(Dimethylamino) phenyl] thiophene-2-carboxamide nanoparticle (DPCNPs) was
synthesized for detect cadmium metal in Aqueous Medium Based on Fluorescent quenching. Cd+2
particularly is emitted into the environment via fertilizers of abundant phosphate, and prolonged Cd+2
contact can cause bone weakening and damage to the internal organs. Its characteristics and fluorescence
behavior were studied. Dynamic light scattering (DLS) was utilized to test the prepared NDPCNPs which
reveal a narrower distribution of the sizes of the particles of 60 nm which is the average particles size.
The scanning electron microphotograph (SEM) shows distinctive nano-particles of morphology in a
spherical shape. The (DPCNPs) aqueous suspension fluorescence spectra and UV-absorption are blue
shifted from the congruous of N-[3-(Dimethylamino) phenyl] thiophene-2-carboxamide solution spectra
in acetonitrile. Such shifted blue color indicates the Aggregation Induced Enhanced Emission (AIEE) and
H-aggregates from nano-particles. The (DPCNPs) nano-particles are of stability being high with
surfactant of Tween80. Therefore, the effects of few metal cations on the fluorescent (DPCNPs) intensity
were investigated. It was detected that fluorescence modified (DPCNPs) intensity was quenched
selectively through Cd (II) ion addition compared to with other tested cations. The (DPCNPs) can be
utilized as chemosensor being fluorescent bulk for Cd (II) ions detection. The quenching of fluorescent is
linear at 25 to 225 µM range of ions of Cd (II). The detection limit was 1.47µM. The nanosensor displays
a great selectivity versus ions of Cd (II) compared to communal metal ions. The suggested method
applicability for detecting Cd+ metal in water samples collected from the Al Habbaniya Lake (Iraq) were
calculated.
Keywords
N-[3-(Dimethylamino) phenyl] thiophene-2-carboxamide, Nano-particles, Sensor, Fluorescent quenching.
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