


Volume 20 No 10 (2022)
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Spectroscopic analysis of surface plasmon resonance in pyrromethene 580 laser dye
QudamaKh. Hammad, Adil N. Ayyash and Falah A-H. Mutlak
Abstract
In this work, spectral properties of (pyromethane 580) PM 580 laser dye were studied
and study the effect of addition Au: Ag Nanoparticles .In this study, studied the spectral
properties of the liquid dye (pyromethane 580) PM 580 dissolved in ethanol solvent with
different concentrations (1x10-3
, 5x10-4
, 1x10-4
, 5x10-5
, 1x10-5
, 1x10-6
) M and the ideal
concentration was chosen at 1x10-6 M. Also, nanoparticles were prepared from the
noble metals (gold and silver) (Au: Ag) NPs immersed in 3 ml of polyvinyl alcohol (PVA)
using a pulsed laser Nd-YAG with wavelengths (532 nm) with a number of 500 pulses
and different energy (400, 600, 800, 1000) mJ. The spectral and structural properties of
the mixture (laser dye and nanoparticles) were also studied. The results of the spectral
properties of the dye solution showed that the peak of the absorption spectrum and the
peak of the fluorescence spectrum of the liquid dye shift towards the shorter
wavelengths (blue shift) when the concentration decreases, while the relative intensity
decreases with the decrease in concentration While the fluorescence spectra were
increased when the concentration was decreased, Observed by varying amount of Au:
Ag NPs, the intensity of absorption and fluorescence are increasing with increasing this
amount
Keywords
Nanoparticles; Pyrromethene 580 dye; quantum yield; Absorpence
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